PALLADIUM-CATALYZED SYNTHESIS OF STEREODEFINED 4-ARYLIDENE-3 TOSYLOXAZOLIDIN-2-ONES FROM 2-PROPYNYL TOSYLCARBAMATES AND UNSATURATED HALIDES(OR TRIFLATE)

Citation
D. Bouyssi et al., PALLADIUM-CATALYZED SYNTHESIS OF STEREODEFINED 4-ARYLIDENE-3 TOSYLOXAZOLIDIN-2-ONES FROM 2-PROPYNYL TOSYLCARBAMATES AND UNSATURATED HALIDES(OR TRIFLATE), Synlett, (8), 1997, pp. 944
Citations number
31
Journal title
ISSN journal
09365214
Issue
8
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):8<944:PSOS4T>2.0.ZU;2-1
Abstract
2-propynyl tosylcarbamates undergo cyclisation-coupling reactions with aryl iodides (and one alkenyl triflate) in the presence of base and o f catalytic amounts of a palladium(0)-phosphine complex to form (E)-4- arylidene or 4-alkylidene-3-tosyloxazolidin-2-ones in a regio-and ster eoselective manner.