Jt. Wang et al., CALCULATED PHASE-DIAGRAMS FOR ACTIVATED LOW-PRESSURE DIAMOND GROWTH FROM C-H, C-O, AND C-H-O SYSTEMS, Journal of materials research, 12(12), 1997, pp. 3250-3253
Three-dimensional temperature (T)-pressure (P)-composition (X) phase d
iagrams of binary carbon-hydrogen (C-H) and carbon-oxygen (C-O) system
s for activated low pressure diamond growth have been calculated. Base
d on an approximation of linear combination between C-H and C-O system
s, a projective ternary carbon-hydrogen-oxygen (C-H-O) phase diagram h
as also been obtained. There is always a diamond growth region in each
of these phase diagrams. Once a supply of external activating energy
stops, the diamond growth region will not exist. Nearly all of the rel
iable experimental data reported in the Literature drop into the possi
ble diamond growth region of the calculated projective ternary C-H-O p
hase diagram under the conditions of 0.01-100 kPa and above 700 K.