Br. Elliott et al., A DESCRIPTIVE MODEL LINKING POSSIBLE FORMATION MECHANISMS FOR GRAPHITE-ENCAPSULATED NANOCRYSTALS TO PROCESSING PARAMETERS, Journal of materials research, 12(12), 1997, pp. 3328-3344
New and modified mechanisms are proposed to account for detailed obser
vations of carbon encapsulation of Fe, Ni, and Co nanocrystals. The me
chanisms are based on aerosol and gas phase chemistry and on the catal
ytic effects of transition metals, Two parameters are found to qualita
tively dominate production: the local-path carbon-to-metal ratio (LCM)
and the global carbon-to-metal ratio (GCM). LCM's select which mechan
isms are active along each pathway within the reactor, The GCM places
bounds upon and determines the weighting between different LCM's and t
hus determines the distribution of different nanoscale products within
the collected, macroscopic product, A two part processing parameter -
-> mechanism --> product map links the components, The generality of t
he model is discussed throughout with reference to related processes a
nd the encapsulation of other materials.