2O4)-O-V)(6)O-4(MU(2)-OH)(12)((MOO3)-O-VI)(4)](6-) AND (((MO2O4)-O-V)(3)(MU(2)-OH)(3)H(PHPO3)(4))(2)](7-) - A FURTHER EXAMPLE FOR THE VALIDITY OF THE CONCEPT OF UNIT CONSTRUCTION IN POLYOXOMETALATE CHEMISTRY

Authors
MULLER A DILLINGER S KRICKEMEYER E BOGGE H PLASS W STAMMLER A HAUSHALTER RC
Citation
A. Muller et al., 2O4)-O-V)(6)O-4(MU(2)-OH)(12)((MOO3)-O-VI)(4)](6-) AND (((MO2O4)-O-V)(3)(MU(2)-OH)(3)H(PHPO3)(4))(2)](7-) - A FURTHER EXAMPLE FOR THE VALIDITY OF THE CONCEPT OF UNIT CONSTRUCTION IN POLYOXOMETALATE CHEMISTRY, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(11), 1997, pp. 1301-1306
Citations number
24
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
11
Year of publication
1997
Pages
1301 - 1306
Database
ISI
SICI code
0932-0776(1997)52:11<1301:2A(>2.0.ZU;2-L
Abstract
The compound Na-7[Na subset of{((Mo2O4)-O-V)(3)(mu 2-OH)(3)H(PhPO3)4}( 2)] . 2 N2H4 . 26 H2O (formulation with respect to the aggregate in th e crystal) has been synthesized and characterized by single-crystal X- ray structure analysis (which alone does not allow the determination o f the formula), UV/Vis/NIR/IR, P-31{H-1}, H-1 and Na-23 NMR spectrosco py as well as magnetic susceptibility measurements. The compound is fo rmed under similar conditions as (NH2Me2)(6)[H-2 subset of (MO2O4)-O-V )(6)O-4(mu(2)-OH)(12)((MOO3)-O-VI)(4)]. Correspondingly, both cluster frameworks are built up by the same {((Mo2O4)-O-V)3(mu(2)-OH)(3)}(3+) units.