SYNTHESIS AND CRYSTAL-STRUCTURES OF DIMERIC TITANIUM(II) BIS(TRIMETHYLSILYL)ACETYLENE COMPLEXES H5-NMEN)TI(ETA(2)-ME3SIC-CSIME3)(MU-CL)](2)(N=3-5)

Authors
HILLER J THEWALT U PODLAHA J HANUS V MACH K
Citation
J. Hiller et al., SYNTHESIS AND CRYSTAL-STRUCTURES OF DIMERIC TITANIUM(II) BIS(TRIMETHYLSILYL)ACETYLENE COMPLEXES H5-NMEN)TI(ETA(2)-ME3SIC-CSIME3)(MU-CL)](2)(N=3-5), Collection of Czechoslovak Chemical Communications, 62(10), 1997, pp. 1551-1561
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
62
Issue
10
Year of publication
1997
Pages
1551 - 1561
Database
ISI
SICI code
0010-0765(1997)62:10<1551:SACODT>2.0.ZU;2-K
Abstract
Crystalline Ti(II) complexes [(C5H5-nMen)Ti(eta(2)-Me3SiC=CSiMe3)(mu-C l)](2) (n = 3-5) (1-3) were prepared by reduction of the appropriate c yclopentadienyltitanium trichlorides (C5H5-nMen)TiCl3 in tetrahydrofur an by one equivalent of magnesium in the presence of at least one equi valent of bis(trimethylsilyl)acetylene. The X-ray structure analyses o f 1-3 revealed that all compounds form chlorine-bridged centrosymmetri c dimers.