We investigate the form of the momentum distribution function for prot
ons and electrons in an advection-dominated accretion flow (ADAF). We
show that for all accretion rates, Coulomb collisions are too ineffici
ent to thermalize the protons. The proton distribution function is the
refore determined by the viscous heating mechanism, which is unknown.
The electrons, however, can exchange energy quite efficiently through
Coulomb collisions and the emission and absorption of synchrotron phot
ons. We find that for accretion rates greater than similar to 10(-3) o
f the Eddington accretion rate, the electrons have a thermal distribut
ion throughout the accretion flow. For lower accretion rates, the elec
tron distribution function is determined by the electron's source of h
eating, which is primarily adiabatic compression. Using the principle
of adiabatic invariance, we show that an adiabatically compressed, col
lisionless gas maintains a thermal distribution until the particle ene
rgies become relativistic. We derive a new, nonthermal distribution fu
nction for relativistic energies and provide analytic formulae for the
synchrotron radiation from this distribution. Finally, we discuss its
implications for the emission spectra from ADAFs.