Photoexcitation of chlorine DX centers induces a transition of the Cl
atoms to the shallow-donor state and persistent photoconductivity at l
ow temperature in Cd0.8Zn0.2Te:Cl. The relaxation of the substitutiona
l Cl atoms to the DX state at 140 K is coincident with a decrease of t
he positron lineshape parameter and an increase of annihilation with h
igh-momentum core electrons. The results indicate positron trapping an
d annihilation at DX centers and at chlorine A centers. The data suppo
rt the bond breaking model of the DX centers and the outward relaxatio
n of the Cl and Cd(Zn) atoms along the [111] direction. The thermal ba
rrier for the shallow-deep transition was found to be 0.44 eV.