NEOGLYCOPOLYMERS PREPARED VIA VINYL POLYMERIZATION OF NEW SUGAR-SUBSTITUTED NORBORNENES, CATALYZED BY PDCL2(TPPTS)(2) IN WATER

Authors
PUECH L PEREZ E RICOLATTES I BON M LATTES A MOISAND A
Citation
L. Puech et al., NEOGLYCOPOLYMERS PREPARED VIA VINYL POLYMERIZATION OF NEW SUGAR-SUBSTITUTED NORBORNENES, CATALYZED BY PDCL2(TPPTS)(2) IN WATER, New journal of chemistry, 21(11), 1997, pp. 1229-1234
Citations number
24
Categorie Soggetti
Chemistry
Journal title
New journal of chemistry → ACNP
ISSN journal
11440546
Volume
21
Issue
11
Year of publication
1997
Pages
1229 - 1234
Database
ISI
SICI code
1144-0546(1997)21:11<1229:NPVVPO>2.0.ZU;2-J
Abstract
Two new sugar-substituted norbornenes, N-methyl norbornylgluconamide a nd N-methyl norbornyllactobionamide, were prepared by the action of 5- methylaminobicyclo[2.2.1]hept-2-ene on delta-gluconolactone and lactob ionic acid, respectively. Vinyl polymerization of these derivatives pr oduced a high yield of neoglycopolymers bearing the norbornane moiety. These amphiphilic polymers were highly soluble in water, forming stab le particles consisting of aggregates of oligomers. The aggregates wer e characterized by light scattering and electron microscopic examinati on.