ROLE OF OS-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-H-N INTERACTIONS IN DIRECTING THE STEREOCHEMISTRY OF CARBONYL CLUSTER HYDRIDE DERIVATIVES

Authors
AIME S GOBETTO R VALLS E
Citation
S. Aime et al., ROLE OF OS-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-H-N INTERACTIONS IN DIRECTING THE STEREOCHEMISTRY OF CARBONYL CLUSTER HYDRIDE DERIVATIVES, Organometallics, 16(24), 1997, pp. 5140-5141
Citations number
6
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
24
Year of publication
1997
Pages
5140 - 5141
Database
ISI
SICI code
0276-7333(1997)16:24<5140:ROOIID>2.0.ZU;2-N
Abstract
Unconventional hydrogen-bond interactions involving metal hydrides as proton acceptors from N-H bonds have been recently discovered in monon uclear organometallic systems. The work herein reported on H2Os3(CO)(1 0)L (L= NH2Et, NHEt2) suggests that this type of interaction may be ev en more important in cluster chemistry in directing the stereochemistr y of the products as well as affecting the intramolecular ligand excha nge processes.