SYNTHESIS, DERIVATIZATION, AND STRUCTURE OF THE SILANETRIOL [C5H4(SIME3)]SI(OH)(3) - UNIQUE HYDROGEN-BONDING IN A HIGHLY SYMMETRICAL TUBULAR ASSEMBLY

Authors
JUTZI P SCHNEIDER M STAMMLER HG NEUMANN B
Citation
P. Jutzi et al., SYNTHESIS, DERIVATIZATION, AND STRUCTURE OF THE SILANETRIOL [C5H4(SIME3)]SI(OH)(3) - UNIQUE HYDROGEN-BONDING IN A HIGHLY SYMMETRICAL TUBULAR ASSEMBLY, Organometallics, 16(24), 1997, pp. 5377-5380
Citations number
19
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
24
Year of publication
1997
Pages
5377 - 5380
Database
ISI
SICI code
0276-7333(1997)16:24<5377:SDASOT>2.0.ZU;2-4
Abstract
imethylsilyl)cyclopenta-1,3-dien-5-yl)silanetriol, [C5H4(SiMe3)]Si(OH) (3) (2), has been synthesized by controlled hydrolysis of the silicon trichloride [C5H4(SiMe3)]SiCl3 (1) The crystal structure of compound 2 confirms a new structure type for silanetriols: intermolecular hydrog en bonding leads to a highly symmetrical tubelike arrangement. Stannyl ation of 2 utilizing N(SnMe3)(3) yields [C5H4(SiMe3)]Si(OSnMe3)(3) (3) as a valuable synthon for the silanetriol.