Jr. Galsworthy et al., SYNTHESES AND CHARACTERIZATION OF AMINO (PENTAFLUOROPHENYL) BORANES -CRYSTAL-STRUCTURE OF [(ME3SI)(2)NB(C6F5)(2)], Polyhedron, 17(1), 1998, pp. 119-124
The chloroborane, ClB(C6F5)(2), has been investigated as a useful synt
hon for the preparation of a series of amino (pentafluorophenyl)borane
s. The compounds [(Me3Si)(2)NB(C6F5)(2)], 1, [(Me3Si)(H)NB(C6F5)(2)],
2, and [HN{B(C6F5)(2)}(2)], 3, synthesised and 1 has been characterise
d by X-ray crystallography. (C) 1997 Elsevier Science Ltd.