SYNTHESIS AND CHARACTERIZATION OF INDIUM(III) COMPLEXES WITH TRIDENTATE AND PENTADENTATE THIOSEMICARBAZONES - CRYSTAL AND MOLECULAR-STRUCTURE OF [INCL2(HDAPTSC)]CENTER-DOT-2DMSO, (O[IN(HDAPTSC)(OH)](2))CENTER-DOT-5MEOH, [INCL2-(APTSC)(MEOH)], [IN(APTSC)(2)]PF6 AND (H(2)APTSC)][INCL(APTSC)(MNT)]CENTER-DOT-0.5H(2)O (H(2)DAPTSC EQUALS 2,6-DIACETYLPYRIDINE-BIS(THIOSEMICARBAZONE),

Authors
ABRAM S MAICHLEMOSSMER C ABRAM U
Citation
S. Abram et al., SYNTHESIS AND CHARACTERIZATION OF INDIUM(III) COMPLEXES WITH TRIDENTATE AND PENTADENTATE THIOSEMICARBAZONES - CRYSTAL AND MOLECULAR-STRUCTURE OF [INCL2(HDAPTSC)]CENTER-DOT-2DMSO, (O[IN(HDAPTSC)(OH)](2))CENTER-DOT-5MEOH, [INCL2-(APTSC)(MEOH)], [IN(APTSC)(2)]PF6 AND (H(2)APTSC)][INCL(APTSC)(MNT)]CENTER-DOT-0.5H(2)O (H(2)DAPTSC EQUALS 2,6-DIACETYLPYRIDINE-BIS(THIOSEMICARBAZONE),, Polyhedron, 17(1), 1998, pp. 131-143
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
1
Year of publication
1998
Pages
131 - 143
Database
ISI
SICI code
0277-5387(1998)17:1<131:SACOIC>2.0.ZU;2-#
Abstract
The synthesis and characterization of novel indium(III) complexes with pyridine-thiosemicarbazone ligands are reported as well as ligand exc hange reactions on the products. 2,6-Diacetylpyridine-bis(thiosemicarb azone), C5H3N(C3N3SH6)(2) (H(2)DAPTSC), and 2-acetylpyridine-thiosemic arbazone, C5H4N(C3N3SH6) (HAPTSC), were reacted with indium(III) halid es and indium(III) nitrate, respectively, to give [InX2(HDAPTSC)], {O[ In(HDAPTSC)(OH)](2)}, [InX2(APTSC)(MeOH)] and [In(APTSC)(2)]PF6. (C) 1 997 Elsevier Science Ltd.