M. Mikuriya et S. Tashima, UNEXPECTED COORDINATION BEHAVIOR OF DINUCLEATING LIGAND - INFINITE ZIGZAG CHAIN OF ALTERNATING SODIUM(I) AND DINUCLEAR-ZINC(II) UNITS, Polyhedron, 17(1), 1998, pp. 207-209
A zinc(II) complex, [Zn4Na2L2(CH3COO)(4)CH3CN](n) . 2nCH(3),CN . 2nH(2
)O (H3L = 2,6-bis(saliclylideneaminomethyl)-4-methylphenol), has been
isolated and characterized by X-ray crystallography, which reveals a u
nique zigzag-chain structure consisting of dinuclear Zn2L(CH3COO)(2) u
nits and sodium ions. (C) 1997 Elsevier Science Ltd.