STEREOCONTROLLED SYNTHESIS OF (+ -)-ALPHA-PINGUISENE AND (+/-)-PINGUISENOL/

Citation
A. Srikrishna et D. Vijaykumar, STEREOCONTROLLED SYNTHESIS OF (+ -)-ALPHA-PINGUISENE AND (+/-)-PINGUISENOL/, Journal of the Chemical Society. Perkin transactions. I, (22), 1997, pp. 3295-3296
Citations number
8
ISSN journal
0300922X
Issue
22
Year of publication
1997
Pages
3295 - 3296
Database
ISI
SICI code
0300-922X(1997):22<3295:SSO(-A>2.0.ZU;2-B
Abstract
Total synthesis of (+/-)-alpha-pinguisene 1 and (+/-)-pinguisenol 2, e mploying an orthoester Claisen rearrangement and an intramolecular dia zo ketone cyclopropanation reaction for the stereospecific constructio n of vicinal quaternary carbon atoms, is described.