STUDIES ON BIS(2,3 5,6-DI-O-ISOPROPYLIDENE-D-MANNOFURANOSYL)AMINE ANDITS PROTECTED AND DEPROTECTED N-ACYL DERIVATIVES - AN APPROACH TO NOVEL NONIONIC SURFACTANTS/
Df. Ewing et al., STUDIES ON BIS(2,3 5,6-DI-O-ISOPROPYLIDENE-D-MANNOFURANOSYL)AMINE ANDITS PROTECTED AND DEPROTECTED N-ACYL DERIVATIVES - AN APPROACH TO NOVEL NONIONIC SURFACTANTS/, Journal of the Chemical Society. Perkin transactions. I, (22), 1997, pp. 3459-3463
Optimum conditions for the formation of N-acyl derivatives of 2,3:5,6-
di-O-isopropylidene-D-mannofuranosyl)amine with long-chain acid chlori
des have been determined, The anomeric equilibrium of the parent bis(s
ugar)amine has been investigated and the amide rotation barrier measur
ed for these protected sugar derivatives and the analogous compounds w
ith the protecting groups removed.