Mje. Richardson, EXACT SOLUTION OF 2-SPECIES BALLISTIC ANNIHILATION WITH GENERAL PAIR-REACTION PROBABILITY, Journal of statistical physics, 89(3-4), 1997, pp. 777-799
The reaction process A + B --> <empty set> is modelled for ballistic r
eactants on an infinite line with particle velocities upsilon(A) = c a
nd upsilon(B) = -c and initially segregated conditions, i.e., all A pa
rticles to the left and all B particles to the right of the origin. Pr
evious models of ballistic annihilation have particles that always rea
ct on contact, i.e., pair-reaction probability p = 1. The evolutions o
f such systems are wholly determined by the initial distributions of p
articles and therefore do not have a stochastic dynamics. However, in
this paper the generalization is made to p less than or equal to 1, al
lowing particles to pass through each other without necessarily reacti
ng. In this way, the A and B particle domains overlap to form a fluctu
ating, finite-sized reaction zone where the product <empty set> is cre
ated. Fluctuations are also included in the currents of A and B partic
les entering the overlap region, thereby inducing a stochastic motion
of the reaction zone as a whole. These two types of fluctuations, in t
he reactions and particle currents, are characterised by the intrinsic
reaction rate, seen in a single system, and the extrinsic reaction ra
te, seen in an average over many systems. The intrinsic and extrinsic
behaviors are examined and compared to the case of isotropically diffu
sing reactants.