We report on the discovery and analysis of a striking neutral sodium g
as tail associated with comet C/1995 O1 Hale-Bopp. Sodium D line emiss
ion has been observed at heliocentric distance r less than or equal to
1.4 AU in some long-period comets, and the presence of neutral sodium
in the tailward direction of a few bright comets has been noted, but
the extent, and in particular the source, has never been clear. Here w
e describe the first observations and analysis of a neutral sodium gas
tail in comet Hale-Bopp, which is entirely different from the previou
sly known ion and dust tails. We show that the observed characteristic
s of this third type of tail are consistent with it being produced by
radiation pressure due to resonance fluorescence of sodium atoms and t
hat the lifetime for photoionization is consistent with recent theoret
ical calculations.