A REMARKABLE TENDENCY OF O-LITHIO-N-(2-LITHIOOXYETHYL)-N-METHYL-ANILINE TO FORM HETEROCYCLIC-DERIVATIVES BY ITS REACTION WITH DICHIORODIALKYLSILANES OR SILICON TETRACHLORIDE - SYNTHESIS OF 2,5,1-BENZOXAZASILEPINES AND OF THE SILASPIRO ANALOG

Authors
KOSTAS ID SCRETTAS CG RAPTOPOULOU CP TERZIS A
Citation
Id. Kostas et al., A REMARKABLE TENDENCY OF O-LITHIO-N-(2-LITHIOOXYETHYL)-N-METHYL-ANILINE TO FORM HETEROCYCLIC-DERIVATIVES BY ITS REACTION WITH DICHIORODIALKYLSILANES OR SILICON TETRACHLORIDE - SYNTHESIS OF 2,5,1-BENZOXAZASILEPINES AND OF THE SILASPIRO ANALOG, Tetrahedron letters, 38(50), 1997, pp. 8761-8764
Citations number
19
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
50
Year of publication
1997
Pages
8761 - 8764
Database
ISI
SICI code
0040-4039(1997)38:50<8761:ARTOO>2.0.ZU;2-L
Abstract
The synthesis of 2,5,1-benzoxazasilepines 3 or the benzoxazasilaspiro compound 4, has been achieved by the reaction of o-lithio-N-(2-lithioo xyethyl)-N-methyl-aniline (2) with R2SiCl2 (R = Me, Et, Ph) or SiCl4, respectively. The reaction led to the formation of cyclic products, ev en under conditions favorable for the formation of polymeric materials . (C) 1997 Elsevier Science Ltd.