O. Johnsen et al., OPTICAL-DATA ON MINERALS OF THE EUDIALYTE GROUP - DISCUSSION OF THE EUCOLITE-MESODIALYTE-EUDIALYTE TERMINOLOGY, Neues Jahrbuch fur Mineralogie Monatshefte, (8), 1997, pp. 371-383
21 samples of eudialyte minerals with high quality electron microprobe
data have been investigated by means of the microrefractometer spindl
e-stage technique. The object of the study is to determine the most si
gnificant correlations between chemical composition and optical proper
ties of this group and on this basis evaluate the eudialyte-mesodialyt
e-eucolite terminology. The measured refractive indices and birefringe
ncies fall within the ranges known from the literature. The majority o
f the samples are optically negative with a low birefringence. The Na
content has no detectable influence on the mean refractive index (n_me
an), while Ca shows a negative correlation to n_mean, opposite that su
ggested in connection to an alleged Na reversible arrow Ca isomorphous
series in the group. The most significant correlations involving n_me
an are positive ones to Dr and to Sigma Nb,REE,Mn,F the kentbrooksite
end-member component. The birefringence shows a good positive correlat
ion to the quantity Nb/(Nb + exSi) that signifies the occupation of th
e sites in the middle of the nine-fold rings. This quantity can howeve
r not be sorted out from the complex substitution found in the eudialy
te-kentbrooksite series. It is concluded that the term eucolite, which
has been used for an optically negative and Ca-rich eudialyte, is mea
ningless and in some respect misleading, so the use of this term shoul
d be discontinued. Mesodialyte as a name for an optically isotropic in
termediate of an inferior if at all existing series should also be abo
lished.