The adiabatic approximation is used to describe the electron states of
weakly-one-dimensional quantum wires. A clear order is evidenced in t
he longitudinal optical (LO) phonon mediated transition rates with res
pect to the quantum numbers of the confined states involved. The avera
ge single electron relaxation time from an excited level is shown eith
er to increase or, surprisingly; to decrease as a function of the init
ial energy. The relaxation of an excited population is dynamically sim
ulated, showing the wire size dependent accelerating and energy loweri
ng effects of an additional phenomenological intrasubband thermalizati
on.