MN-55, (CO)-C-13 AND MN-55, P-31 COUPLING-CONSTANTS OF ORGANOMANGANESE COMPLEXES - COMPARISON OF NMR RESULTS FROM EXPERIMENTS IN SOLUTION AND IN THE SOLID-STATE

Scalar spin-spin coupling constants of some organomanganese complexes, Mn(CO)(5-n)(R)L-n, were evaluated by lineshape analysis from C-13 and P-31 solution NMR spectra and from solid-state magic angle spinning s pectra showing first-order splitting. Consistent results were obtained for favourable complexes, but each method has only limited applicabil ity in the general case. The merits of both methods are discussed. (C) 1997 John Wiley & Sons, Ltd.