CARBAMOYLETHYLATION OF MOGHAT MUCILAGE

Citation
Aa. Ragheb et al., CARBAMOYLETHYLATION OF MOGHAT MUCILAGE, Die Angewandte makromolekulare Chemie, 251, 1997, pp. 23-35
Citations number
28
ISSN journal
00033146
Volume
251
Year of publication
1997
Pages
23 - 35
Database
ISI
SICI code
0003-3146(1997)251:<23:COMM>2.0.ZU;2-B
Abstract
Mucilage isolated from the grinded roots of Glossostemon bruguieri (De sf.) (moghat) was subjected to carbamoylethylation, which involved the reaction of the moghat mucilage with acrylamide along with sodium hyd roxide as a catalyst. The reaction was found to depend on the acrylami de concentration as well as on temperature. While the extent of carbam oylethylation increases by increasing acrylamide concentration from 20 to 100 g/100 g mucilage, it decreases by raising the reaction tempera ture from 25 degrees C to 75 degrees C. The carbamoylethylated moghat mucilage exhibits non-Newtonian pseudoplastic behaviour irrespective o f the extent of carbamoylethylation. On the other hand, increasing the extent of carbamoylethylation is accompanied by an enhancement in the apparent viscosity. This was evidenced by the direct relation of the apparent viscosity with the increase in acrylamide concentration and i ts inverse relation with the temperature. A 72 h storage of the pastes under investigation causes a considerable decrement in apparent visco sity only when the extent of carbamoylethylation is low. Higher extent s of carbamoylethylation stabilised the molecular structure of the mog hat mucilage.