Starch constitutes a major component of foods and also a raw material
for use in the production of industrial products. The constituent macr
omolecules of starch are packaged in a highly ordered and compact mann
er, resulting in inert insoluble granules. Food processing destroys st
arch structure, thereby releasing the component molecules, which are s
ubsequently mad available for hydrolysis or serve a functional role in
the food system. The application of starch as a raw material usually
requires the prior disruption of the inert granule structure, which in
volves additional processing steps. The hydrolysis of native granules
has ramifications at all levels of the food processing chain, from pos
tharvest losses to nutritional consequences of the ingested food. Tech
nologists have not been able to take advantage of, or control, this pr
ocess because the body of the information that is available on starch
granule structure and the behaviour of hydrolysing enzymes is still in
complete. In this review, I have highlighted some of the more recent a
dvances in this field, with the view to opening up the way for more ef
ficient native starch hydrolysis.