ELECTROCHEMICAL REDUCTION OF THE RHODIUM(III) OXALATE COMPLEXES ON MERCURY COMPLICATED BY THE HYDROXONIUM ION DISCHARGE

Authors
ASTAKHOVA RK BALUSHKINA SR MALEV VV
Citation
Rk. Astakhova et al., ELECTROCHEMICAL REDUCTION OF THE RHODIUM(III) OXALATE COMPLEXES ON MERCURY COMPLICATED BY THE HYDROXONIUM ION DISCHARGE, Russian journal of electrochemistry, 33(11), 1997, pp. 1273-1276
Citations number
11
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
33
Issue
11
Year of publication
1997
Pages
1273 - 1276
Database
ISI
SICI code
1023-1935(1997)33:11<1273:EROTRO>2.0.ZU;2-O
Abstract
The reduction kinetics of the rhodium(III) oxalate complexes is studie d in a sodium sulfate supporting electrolyte by the polarography, cycl ic voltammetry (CVA), and coulometry methods. A three-electron reducti on of the rhodium(III) complexes is shown to occur with the slow attac hment of the first electron complicated by discharge of the hydroxoniu m ions.