The wear behaviour of a number of engineering ceramics sliding against
polyethyleneterephthalate (PET) has been examined. Microscopical exam
ination of the worn surfaces has shown a wide distribution of size of
grooves, from 50 nm to 1 mu m. The smaller grooves seem to be made by
anatase particles in the PET sheet. The larger grooves are made by par
ticles ejected from the samples' surfaces by a fatigue mechanism. By r
elating the hardness of the engineering ceramics at a scale appropriat
e to the measured wear rates, some degree of agreement found. Further,
it was found that the near-surface hardness of all the materials was
lower than the macroscopic hardness values: the sole exception was ana
tase. Although the macroscopic hardness values of anatase were much lo
wer than the alumina-based ceramics, the near-surface hardness values
became relatively greater. In this way, what was originally thought to
be a ''soft'' ceramic can now abrade a nominally ''harder'' one. The
wear of the carbides is thought to be by an oxidation-assisted process
.