AN INFREQUENT GEOMETRY FOR AN ELEMENT OF THE FIRST TRANSITION SERIES - STRUCTURAL CHARACTERIZATION OF A DISTORTED 8-COORDINATE COMPOUND TICL4[C2H4(PME2)(2)](2)

Authors
COTTON FA MATONIC JH MURILLO CA PETRUKHINA MA
Citation
Fa. Cotton et al., AN INFREQUENT GEOMETRY FOR AN ELEMENT OF THE FIRST TRANSITION SERIES - STRUCTURAL CHARACTERIZATION OF A DISTORTED 8-COORDINATE COMPOUND TICL4[C2H4(PME2)(2)](2), Inorganica Chimica Acta, 267(1), 1998, pp. 173-176
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
267
Issue
1
Year of publication
1998
Pages
173 - 176
Database
ISI
SICI code
0020-1693(1998)267:1<173:AIGFAE>2.0.ZU;2-6
Abstract
An eight-coordinate complex, TiCl4[C2H4(PMe2)(2)](2) (1), has been pre pared and crystallographically characterized. A distorted arrange ment of four chlorine and four phosphorus atoms has been found far the Ti- IV center with the following bond lengths: Ti-Cl, 2.446(1) and 2.451(1 ) Angstrom, and Ti-P, 2.648(1) and 2.654(1) Angstrom. (C) 1998 Elsevie r Science S.A.