ONE-POT SYNTHESIS OF SECONDARY AND TERTIARY-AMINES BY CARBONYLATIVE HYDROAMINOMETHYLATION OF ALKENES CATALYZED BY (MU-CHLORO)BIS(ETA(4)-1,5-CYCLOOCTADIENE)DIRHODIUM

Authors
RISCHE T EILBRACHT P
Citation
T. Rische et P. Eilbracht, ONE-POT SYNTHESIS OF SECONDARY AND TERTIARY-AMINES BY CARBONYLATIVE HYDROAMINOMETHYLATION OF ALKENES CATALYZED BY (MU-CHLORO)BIS(ETA(4)-1,5-CYCLOOCTADIENE)DIRHODIUM, Synthesis, (11), 1997, pp. 1331-1337
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
11
Year of publication
1997
Pages
1331 - 1337
Database
ISI
SICI code
0039-7881(1997):11<1331:OSOSAT>2.0.ZU;2-W
Abstract
Secondary and tertiary amines are selectively prepared with high yield s by the reaction of alkenes with primary or secondary amines, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl](2) as catalyst vi a a one-pot hydroformylation - amine condensation - reduction sequence .