Desorption of long-lived neutral particles from solid Ne is studied us
ing selective photoexcitation and time of flight (TOF) techniques. The
luminescence due to direct light from the sample surface is blocked b
y rotating the sample. Two new prominent features are revealed in the
TOF spectra measured with the special geometry in the study: a promine
nt long tail and a maximum at the delay time of 0.5 ms. From the analy
sis of the excitation spectra recorded by a time-window technique and
the TOF spectra at selective excitation, it is considered that the new
features are closely related to Ne-2 excimer desorption. An analysis
of the probable mechanisms of long life-time emission is presented. (
C) 1997 Elsevier Science B.V.