APPLICATION OF (2R,3R)-DIHYDROXY-1,2,3,4-TETRAHYDRONAPHTHALENE TO ASYMMETRIC-SYNTHESIS

Authors
ORSINI F RINALDI S
Citation
F. Orsini et S. Rinaldi, APPLICATION OF (2R,3R)-DIHYDROXY-1,2,3,4-TETRAHYDRONAPHTHALENE TO ASYMMETRIC-SYNTHESIS, Tetrahedron : asymmetry, 8(7), 1997, pp. 1039-1048
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
7
Year of publication
1997
Pages
1039 - 1048
Database
ISI
SICI code
0957-4166(1997)8:7<1039:AO(TA>2.0.ZU;2-N
Abstract
(2R,3R)-Dihydroxy-tetrahydronaphthalene, prepared via an efficient che moenzymatic procedure from naphthalene, has been successfully tested, as a chiral auxiliary in diastereoselective conjugate additions of lit hium dialkylcuprates to alpha,beta-unsaturated esters and in stereosel ective alkylations of beta-ketoesters. (C) 1997 Published by Elsevier Science Ltd.