SYNTHESIS OF NEW CHIRAL N-SUBSTITUTED FUSED PYRAZOLES AND PYRAZOLINOLS

Authors
POPOV SA SHAKIROV MM TKACHEV AV DEKIMPE N
Citation
Sa. Popov et al., SYNTHESIS OF NEW CHIRAL N-SUBSTITUTED FUSED PYRAZOLES AND PYRAZOLINOLS, Tetrahedron, 53(52), 1997, pp. 17735-17750
Citations number
14
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
52
Year of publication
1997
Pages
17735 - 17750
Database
ISI
SICI code
0040-4020(1997)53:52<17735:SONCNF>2.0.ZU;2-X
Abstract
Treatment of beta-diketones and the corresponding beta-enaminoketones, having modified carane (2-ethyl-6,6-dimethylbicyclo[3.1.0]hexane) and p-menthane (3-ethyl-1-isopropylcyclopentane) skeletons, with aryl-and alkylhydrazines results in regioselective formation of N-substituted pyrazoles or stable pyrazolinols depending on the nature of the substi tuent at the hydrazine nitrogen. (C) 1997 Elsevier Science Ltd.