AN INTRAMOLECULAR DIELS-ALDER APPROACH TO THE SPIROTETRONIC ACID SUBUNITS OF THE QUARTROMICINS

Authors
ROUSH WR BARDA DA
Citation
Wr. Roush et Da. Barda, AN INTRAMOLECULAR DIELS-ALDER APPROACH TO THE SPIROTETRONIC ACID SUBUNITS OF THE QUARTROMICINS, Tetrahedron letters, 38(51), 1997, pp. 8781-8784
Citations number
31
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
51
Year of publication
1997
Pages
8781 - 8784
Database
ISI
SICI code
0040-4039(1997)38:51<8781:AIDATT>2.0.ZU;2-0
Abstract
Three of the four diastereomeric spirotetronates (2, 19 and 24) corres ponding to the quartromicins were synthesized by a sequence featuring the intramolecular Diels-Alder reaction of 3. An olefin isomerization pathway accounts for formation of the second most abundant cycloadduct , 16. (C) 1997 Elsevier Science Ltd.