[3-CYCLOADDITION REACTIONS OF ALKYNYL(PHENYL)IODONIUM TRIFLATES WITH ETHYL DIAZOACETATE, N-T-BUTYL-ALPHA-PHENYL NITRONE AND T-BUTYLNITRILEOXIDE AS 1,3-DIPOLES(2])
Pj. Stang et P. Murch, [3-CYCLOADDITION REACTIONS OF ALKYNYL(PHENYL)IODONIUM TRIFLATES WITH ETHYL DIAZOACETATE, N-T-BUTYL-ALPHA-PHENYL NITRONE AND T-BUTYLNITRILEOXIDE AS 1,3-DIPOLES(2]), Tetrahedron letters, 38(51), 1997, pp. 8793-8794
The [3+2]-cycloaddition of various beta-substituted ethynyliodonium sa
lts, RC=CIOTf+-, with ethyl diazoacetate, N-t-butyl-alpha-phenyl nitro
ne and t-butylnitrile oxide results in single regioisomeric pyrroles,
dihydroisoxazoles, and isoxazoles respectively in moderate yields. (C)
1997 Elsevier Science Ltd.