STEREOCONTROLLED ACCESS TO CARBA-C-DISACCHARIDES VIA FUNCTIONALIZED DIENYLSILANES

Authors
ANGELAUD R LANDAIS Y PARRARAPADO L
Citation
R. Angelaud et al., STEREOCONTROLLED ACCESS TO CARBA-C-DISACCHARIDES VIA FUNCTIONALIZED DIENYLSILANES, Tetrahedron letters, 38(51), 1997, pp. 8845-8848
Citations number
17
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
51
Year of publication
1997
Pages
8845 - 8848
Database
ISI
SICI code
0040-4039(1997)38:51<8845:SATCVF>2.0.ZU;2-V
Abstract
We report here the total synthesis of a class of Cl --> C6 Carba-C-dis accharide, formed by the association between a 2-deoxyglucose as the s ugar unit and a pseudo-pyranose or a pseudo-furanose as the carba-suga r moiety. The carba-sugar fragments were assembled from the correspond ing dienylsilanes through a dihydroxylation-cyclopropanation sequence. (C) 1997 Elsevier Science Ltd.