ANTI-KISHI SELECTIVE DIHYDROXYLATION OF ALLYLIC ALCOHOL DERIVATIVES

Authors
KALLATSA OA KOSKINEN AMP
Citation
Oa. Kallatsa et Amp. Koskinen, ANTI-KISHI SELECTIVE DIHYDROXYLATION OF ALLYLIC ALCOHOL DERIVATIVES, Tetrahedron letters, 38(51), 1997, pp. 8895-8898
Citations number
26
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
51
Year of publication
1997
Pages
8895 - 8898
Database
ISI
SICI code
0040-4039(1997)38:51<8895:ASDOAA>2.0.ZU;2-X
Abstract
A highly diastereoselective dihydroxylation protocol has been develope d for acyclic allylic alcohol derivatives leading to triol derivatives with diastereoselectivity reversed to the classical osmylation (anti- Kishi). Selectivities are acceptable for E-allylic derivatives 1, and high for those derived from Z-derivatives 4. (C) 1997 Elsevier Science Ltd.