GOLD(I) COMPLEXES WITH AMINE LIGANDS .1. A NOVEL STOICHIOMETRY FOR CHLOROGOLD(I) COMPLEXES - STRUCTURE OF L4AU3CL3 (L = PYRROLIDINE)

Authors
JONES PG AHRENS B
Citation
Pg. Jones et B. Ahrens, GOLD(I) COMPLEXES WITH AMINE LIGANDS .1. A NOVEL STOICHIOMETRY FOR CHLOROGOLD(I) COMPLEXES - STRUCTURE OF L4AU3CL3 (L = PYRROLIDINE), Chemische Berichte, 130(12), 1997, pp. 1813-1814
Citations number
9
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
12
Year of publication
1997
Pages
1813 - 1814
Database
ISI
SICI code
0009-2940(1997)130:12<1813:GCWAL.>2.0.ZU;2-X
Abstract
The reaction between (tht)AuCl (tht = tetrahydrothiophene) and neat py rrolidine (L) leads to the compound L4Au3Cl3. An X-ray structure deter mination reveals the presence of molecules LAuCl and ions L2Au+ and Cl -, in the ratio 2:1:1. The packing is characterised by Au...Au contact s and N-H...Cl- hydrogen bonds.