The features of chlorine plasma interaction with a silicon single crys
tal on the cathode in a glow discharge were studied. It was shown that
the interaction of chlorine with silicon in the range 540-670 K follo
wed the first-order rate law and was characterized by complete removal
of reaction products from the surface. The actual process of silicon
etching is complex in nature and constitutes the combination of chemic
al interaction of chlorine atoms and ions produced in the discharge an
d ion cleaning of active sites.