IRON(III) OXAMATO-CATALYZED EPOXIDATION OF ALKENES BY DIOXYGEN AND PIVALALDEHYDE

Authors
RUIZ R TRIANNIDIS M AUKAULOO A JOURNAUX Y FERNANDEZ I PEDRO JR CERVERA B CASTRO I MUNOZ MC
Citation
R. Ruiz et al., IRON(III) OXAMATO-CATALYZED EPOXIDATION OF ALKENES BY DIOXYGEN AND PIVALALDEHYDE, Chemical communications, (23), 1997, pp. 2283-2284
Citations number
15
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
23
Year of publication
1997
Pages
2283 - 2284
Database
ISI
SICI code
1359-7345(1997):23<2283:IOEOAB>2.0.ZU;2-R
Abstract
A new iron(III)-carbonato monomeric complex of ortho-phenylenebis(oxam ato) (opba) 1 is synthesized, and spectroscopically and structurally c haracterized; it is a moderately efficient non-heme catalyst for the a erobic epoxidation of alkenes with co-oxidation of pivalaldehyde.