FIRST EVIDENCE OF THE FORMATION OF 5,8-ENDOPEROXIDE FROM THE OXIDATION OF 1,4-DISUBSTITUTED NAPHTHALENE BY SINGLET OXYGEN

Authors
PIERLOT C AUBRY JM
Citation
C. Pierlot et Jm. Aubry, FIRST EVIDENCE OF THE FORMATION OF 5,8-ENDOPEROXIDE FROM THE OXIDATION OF 1,4-DISUBSTITUTED NAPHTHALENE BY SINGLET OXYGEN, Chemical communications, (23), 1997, pp. 2289-2290
Citations number
12
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
23
Year of publication
1997
Pages
2289 - 2290
Database
ISI
SICI code
1359-7345(1997):23<2289:FEOTFO>2.0.ZU;2-M
Abstract
Bulky water-soluble 1,4-disubstituted naphthalenes react with singlet oxygen giving the usual 1,4- and the unexpected 5,8-endoperoxides and showing that the regioselectivity of the [4 + 2] cycloaddition of sing let oxygen depends on the steric hindrance of the substrate.