X-RAY CRYSTAL-STRUCTURE OF (TETRAPHENYLIMIDODIPHOSPHINATO)SILVER(I) AN UNEXPECTED TETRANUCLEAR COMPLEX WITH 2 MODES OF COORDINATION OF SILVER

Authors
RUDLER H DENISE B GREGORIO JR VAISSERMANN J
Citation
H. Rudler et al., X-RAY CRYSTAL-STRUCTURE OF (TETRAPHENYLIMIDODIPHOSPHINATO)SILVER(I) AN UNEXPECTED TETRANUCLEAR COMPLEX WITH 2 MODES OF COORDINATION OF SILVER, Chemical communications, (23), 1997, pp. 2299-2300
Citations number
25
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
23
Year of publication
1997
Pages
2299 - 2300
Database
ISI
SICI code
1359-7345(1997):23<2299:XCO(A>2.0.ZU;2-K
Abstract
Potassium tetraphenylimidodiphosphinate reacts with silver nitrate to give, upon recrystallization from ethanol, an unexpected tetranuclear complex [Ag{N(OPPh2)(2)}](4) . 2EtOH, the structure of which is establ ished by X-ray crystallography; preliminary results concerning its use as a catalyst for the aerobic co-oxidation of alkenes and aldehydes a re described.