BIFUNCTIONAL CATALYTIC MEMBRANE CONTAINING BRONSTED ACIDS AND SITES FOR ENANTIOSELECTIVE HYDROGENATION

Authors
TAS D THOELEN C VANKELECOM IFJ JACOBS PA
Citation
D. Tas et al., BIFUNCTIONAL CATALYTIC MEMBRANE CONTAINING BRONSTED ACIDS AND SITES FOR ENANTIOSELECTIVE HYDROGENATION, Chemical communications, (23), 1997, pp. 2323-2324
Citations number
9
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
23
Year of publication
1997
Pages
2323 - 2324
Database
ISI
SICI code
1359-7345(1997):23<2323:BCMCBA>2.0.ZU;2-6
Abstract
The hydrogenation of methyl acetoacetate to give optically pure methyl 3-hydroxybutyrate is performed heterogeneously with high activity and enantioselectivity under mild reaction conditions due to the combinat ion of Bronsted acid and Ru-binap sites in a polydimethylsiloxane memb rane matrix.