We have observed the production of HeH+ ions by the bombardment of gas
eous mixtures of H-2 and He with slow positrons and measured its depen
dence on the positron energy. The formation is believed to involve vib
rational excitation of H-2(+) via positronium formation, followed by p
roton transfer from H-2(+) to He. The significance of these results wi
th respect to astrophysics is discussed. [S1050-2947(97)51012-2].