Low-energy electrons emitted during the interaction of N6+ ions with a
Au surface were measured. The projectile energy was varied in a wide
range from 90 eV to 60 keV. A single-stage spectrometer was used to ac
hieve reliable electron measurements at energies as low as a few eV. T
he experimental data are compared with simulations based on the classi
cal over-the-barrier model. For slow projectiles the observed low-ener
gy electrons are attributed to autoionizing transitions in high Rydber
g states of the projectile. The autoionization electrons provide a sig
nature for the first deexcitation steps of hollow atoms formed above t
he surface. [S1050-2947(97)03211-3].