We have extended the recently developed dynamical classical over-barri
er model for charge transfer in soft ion-cluster collisions in order t
o simulate the projectile kinetic energy gain of 3.3q-keV Arq+ ions in
large-impact-parameter collisions with neutral C-60 targets. Our semi
classical theory allows for the direct calculation of the energy defec
t Q and of the projectile kinetic-energy gain in two different ways: e
ither as difference of electronic binding energies before and after th
e collision or by integration of the dynamically varying force between
the collision partners along the trajectory. A comparison between the
two ways provides an intrinsic test of the model calculations. A comp
arison with recent experimental data shows good agreement in the main
features of the projectile energy gain spectra and facilitates their i
nterpretation in terms of the number of transferred electrons and proj
ectile shells into which electrons are captured. [S1050-2947(97)04512-
5].