M. Boustani et al., CHARACTERIZATION OF CUINTE2 THIN-FILMS PREPARED BY FLASH EVAPORATION, Semiconductor science and technology, 12(12), 1997, pp. 1658-1661
Thin films of CuInTe2 were grown by flash evaporation. The influence o
f the substrate temperature T-s during film deposition on the properti
es of the thin films was examined. CuInTe2 films were structurally cha
racterized by the grazing incidence x-ray diffraction (GIXD) technique
. Investigation by this technique demonstrates that the surface of thi
n films of CuInTe2 prepared by flash evaporation at T-s greater than o
r equal to 100 degrees C exhibits the chalcopyrite structure with addi
tional binary compounds in the surface. However, in the volume the fil
ms exhibit the chalcopyrite structure only; no foreign phases were obs
erved. X-ray reflectometry was utilized to evaluate the critical refle
ction angle beta(c) of CuInTe2 (beta(c)(CuInTe2) approximate to 0.32 d
egrees) which permitted us to calculate the density of the films to be
rho approximate to g cm(-3). The evaporated films were p type and the
films deposited at T-s = 100 degrees C had a resistivity in the range
0.3-2 Omega cm. From optical measurements we have determined the opti
cal energy gap E-g approximate to 0.94 eV and the effective reduced ma
ss m(r)() approximate to 0.07m(e).