BIS(N,N'-DIMETHYLTHIOUREA-S)GOLD(I) PERCHLORATE AND BIS(N,N'-DIETHYLTHIOUREA-S)GOLD(I) PERCHOLORATE

Authors
STAPLES RJ FACKLER JP COSTAMAGNA J
Citation
Rj. Staples et al., BIS(N,N'-DIMETHYLTHIOUREA-S)GOLD(I) PERCHLORATE AND BIS(N,N'-DIETHYLTHIOUREA-S)GOLD(I) PERCHOLORATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1555-1558
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
11
Pages
1555 - 1558
Database
ISI
SICI code
0108-2701(1997)53:<1555:BPAB>2.0.ZU;2-B
Abstract
The gold(I) center in each of the title complexes, [Au(C3H8N2S)(2)]ClO 4, (1), and [AU(C5H12N2S)(2)]ClO4, (2), is essentially linearly coordi nated through the S atoms of the dialkylthiourea ligands. The complexe s crystallize in pairs, with an Au ... Au separation of 3.620(4) and 4 .294(2) Angstrom for (1) and (2), respectively. The perchlorate anion does not interact with the bis(alkylthiourea)gold(I) cation. Compound (1) sits on a twofold axis.