THIOBENZYLIDENE)-1,2-PHENYLENEDIAMINATO]NICKEL(II)

Authors
SMEETS WJJ SPEK AL HENDERSON RK BOUWMAN E REEDIJK J
Citation
Wjj. Smeets et al., THIOBENZYLIDENE)-1,2-PHENYLENEDIAMINATO]NICKEL(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1564-1566
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
11
Pages
1564 - 1566
Database
ISI
SICI code
0108-2701(1997)53:<1564:T>2.0.ZU;2-W
Abstract
The title compound, [Ni(C20H14N2S2)], was formed from a Schiff base re action of 2-tert-butylthiobenzaldehyde with 1,2-phenylenediamine, foll owed by reaction with Ni(BF4)(2).6H(2)O. The square-planar NiN2S2 comp lex has Ni-N distances of 1.8992(17) and 1.9014(15)Angstrom, and Ni C distances of 2.1519(6) and 2.1587 (6) Angstrom. Molecules pack in laye rs with a tilt angle of 46.09(1)degrees; the (001) packing plane is ar ranged so that the molecules in superimposed layers stack approximatel y perpendicular to each ether.