THE SECONDARY EXPLOSIVE RAAMMINE-CIS-BIS(5-NITRO-2H-TETRAZOLATO-N-2)COBALT PERCHLORATE AT 293 AND 213 K

Authors
MOROSIN B DUNN RG ASSINK R MASSIS TM FRONABARGER J DUESLER EN
Citation
B. Morosin et al., THE SECONDARY EXPLOSIVE RAAMMINE-CIS-BIS(5-NITRO-2H-TETRAZOLATO-N-2)COBALT PERCHLORATE AT 293 AND 213 K, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1609-1611
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
11
Pages
1609 - 1611
Database
ISI
SICI code
0108-2701(1997)53:<1609:TSER>2.0.ZU;2-G
Abstract
For the title compound, (OC-6-22)-[Co(CN5O2)(2)-(NH3)(4)]ClO4, the str ucture determination confirms the cis relationship of the two ring lig ands deduced from NMR and shows that these ligands involve N-2 bonding to the Co atom. The accompanying low-temperature study suggests sever al O atoms of the ClO4- ion are slightly disordered rather than having large thermal displacements.