UNUSUAL SUBSTITUTION OF -SCH3 BY -OH IN 9,10-DIHYDROPHENANTHRENE

Citation
S. Sarkhel et al., UNUSUAL SUBSTITUTION OF -SCH3 BY -OH IN 9,10-DIHYDROPHENANTHRENE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1713-1714
Citations number
7
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
11
Pages
1713 - 1714
Database
ISI
SICI code
0108-2701(1997)53:<1713:USO-B->2.0.ZU;2-9
Abstract
The unusual nucleophilic substitution of methylthio by a hydroxyl grou p in the presence of alkali and dimethylformamide in the synthesis of methyl -7-methoxy-9,10-dihydrophenanthrene-4-carboxylate, C23H19ClO4, has been confirmed by single-crystal X-ray structure determination.