K. Contractor et al., INTERACTION OF PEO-PS-PEO BLOCK-COPOLYMERS WITH IONIC SURFACTANTS IN AQUEOUS-SOLUTION, Journal of macromolecular science. Pure and applied chemistry, A34(12), 1997, pp. 2497-2507
The formation of polyelectrolyte type complex by the interaction betwe
en ionic (anionic and cationic) surfactant and block copolymer in wate
r was observed from viscosity measurements. Interaction between the tw
o was also examined from conductance and surface tension measurements
were two transitions, one below and one above the critical micelle con
centration, CMC, of the surfactants were observed. A possible mechanis
m for such an interaction is proposed.