Yh. Wang et al., DIAMOND NANOSPHERULITE - A NOVEL MATERIAL PRODUCED AT CARBON-WATER INTERFACE BY PULSED-LASER ABLATION, Science in China. Series B, Chemistry, life sciences & earth sciences, 40(6), 1997, pp. 608-615
Formation of carbon nanoparticles with perfectly spherical shape and d
iamond structure (diamond nanospherulite) by laser-ablating a variety
of carbon samples in water is reported for the first time. The studies
reveal that molten carbon nanoparticles; generated by laser ablation
are quenched directly by water and end up as diamond nanospherulites,
possibly due to the high pressure arising from surface tension and the
high stability resulting from termination of dangling bonds with hydr
ogen, atoms.